https://help.vrchat.com/hc/en-us/articles/4408619131795-Video-Players-failing-with-CERTIFICATE-VERIFY-FAILED-in-output-logs
Installing these files it required for making Let's encrypt certificates work on PC on AVPro players with this version of Unity.
Not sure if Quest has the same issue, wasn't tested.
It should be added to the documentation that to have a universally useful resolver one needs a SSL certificate other than Let's encrypt.
A solution I figured out is that you can use Cloudflare's proxy to get a valid SSL certificate, since their Universal SSL replaces your server's SSL certificate with their own.